N-(4-Methylbenzyl)-3-nitroaniline
نویسندگان
چکیده
In the title compound, C(14)H(14)N(2)O(2), the angle between the mean plane of the N-methyl-3-nitro-aniline system (r.m.s. deviation = 0.0185 Å) and the p-tolyl unit is 89.79 (4)°. In the crystal, hydrogen-bonded chains running along [10-1] are generated by the linking of neighbouring mol-ecules via N-H⋯O and C-H⋯O hydrogen bonds involving the 3-nitro-aniline systems and forming R(2) (2)(8) motifs.
منابع مشابه
4-[(4-Methylbenzyl)amino]-3-[(4-methylbenzyl)iminomethyl]-2H-chromen-2-one
The title compound, C(26)H(24)N(2)O(2), was prepared from the reaction of 4-chloro-3-formyl-coumarin with p-methyl-benzyl-amine. Even though there are no strong and specific inter-actions in the crystal structure, the translationally related mol-ecules form chains along the b axis. The coumarin moieties are stacked through π-π inter-actions [centroid-centroid distance = 3.5275 (7) Å], forming l...
متن کاملN-[(E)-4-(Methylsulfonyl)benzylidene]-3-nitroaniline
In the title compound, C(14)H(12)N(2)O(4)S, the dihedral angle between the two aromatic rings is 35.65 (12)°. The crystal packing is stabilized by weak C-H⋯O hydrogen bonds and aromatic π-π ring stacking inter-actions [minimum ring centroid separation = 3.697 (3) Å].
متن کامل5-(4-Methylpiperazin-1-yl)-2-nitroaniline
In the title compound, C(11)H(16)N(4)O(2), the dihedral angle between the benzene ring and the plane of the four carbon atoms in the piperazine ring is 12.17 (3)°; the latter ring adopts a chair conformation. An intramolecular N-H⋯O hydrogen bond generates an S(6) ring. In the crystal, the molecules are linked by N-H⋯N hydrogen bonds, forming chains.
متن کامل(E)-N-(3,3-Diphenylallylidene)-4-nitroaniline
In the title compound, C(21)H(16)N(2)O(2), the dihedral angles between the mean planes of the 4-nitro-phenyl ring and the two phenyl rings are 57.3 (5) and 16.8 (6)°. The imine group displays a C-C-N-C torsion angle of -24.9 (3)°.
متن کامل4-Nitroaniline–picric acid (2/1)
In the title adduct, C(6)H(3)N(3)O(7)·0.5C(6)H(6)N(2)O(2), the complete 4-nitro-aniline mol-ecule is generated by a crystallographic twofold axis with two C atoms and two N atoms lying on the axis. The mol-ecular components are linked into two dimensional corrugated layers running parallel to the (001) plane by a combination of inter-molecular N-H⋯O and C-H⋯O hydrogen bonds. The phenolic oxygen...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012